What's in a Clay? Finding the right minerals for Salt Glaze Pottery | KQED (2024)


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What's in a Clay? Finding the right minerals for Salt Glaze Pottery | KQED (1)Clay minerals found naturally in soils around the U.S. and world form the three main types of clay used in pottery: porcelain, earthenware, and stoneware. A unique combination of the minerals kaolin, illite, chlorite, sepiolite, and smectite are collected into each ball of clay to determine the type, glaze, structure and color used in a single piece of pottery.

Potters base their mixture of clay on the plasticity of each material. Plasticity is “the ability to undergo deformation without cracking.” The easiest way to determine a clay’s plasticity is using the “coil” test where a sample of clay is taken, rolled into a coil, and tested for its deformability. The chemical make-up in each clay mineral determines the particle size, permeability, and firing temperature for a piece of pottery. Between the five main minerals found in clay, kaolinite is the most common.

Kaolinite holds the chemical composition Al2Si2O5(OH)4 and is an aluminum silicate material with a low “shrink-swell” capacity. It is a soft, white mineral but is often colored orange or red by iron oxide found in the soil. Kaolinite is found all over the country and is the most common clay in the Mountain and Piedmont regions of North Carolina. It is the most prominent mineral found in kaolin, or porcelain, pottery.

Illite is a white clay mineral that was first discovered in Calhoun County, Illinois. Its composition is (K,H3O)(Al,Mg,Fe)2(Si,Al)4O10[(OH)2,(H2O)]. Illite has an absence of swelling due to its tightly interlaced molecular spacing. It is a common mineral found in sediments, soils, and metamorphic rock.

Chlorite, found in large quantities in Wales, is actually a group of silicate minerals with similar properties. Chlorite, typically found as a pale green to grey color, is composed of (Mg,Fe)3(Si,Al)4O10(OH)2.(Mg,Fe)3(OH)6. The combination of minerals allows chlorite to hold a great range in composition, temperature and pressure conditions. It is most commonly found in hydrothermal ore deposits and has a soft, flexible consistency.

Sepiolite is a clay mineral found throughout in high quantities in New England, Arizona, and California. Its chemical makeup Mg4Si6O15(OH)2·6H2O contains a hydrous magnesium silicate, causing a non-swelling, lightweight, porous clay. Sepiolite based clays are stable in high salt environments and are typically found as dull, white colored deposits.

Smectite clay minerals are unique in their ability to interaction with liquids and their finite crystal shape. The composition (Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2·nH2O causes a high plasticity allowing Smecitite clays to absorb and swell easily. These can be found as white, pale green, pink and yellow deposits.

What's in a Clay? Finding the right minerals for Salt Glaze Pottery | KQED (2024)

FAQs

What are the 3 minerals found in clay? ›

Clay minerals are made up of three members (the illite group), which include illite, glauconite, and muscovite, and display clay-like characteristics, with illite being the most frequent. Illite is generated by alkaline weathering of potassium and aluminum-rich rocks such as muscovite and feldspar.

What are the 2 most essential minerals in clay and glazes? ›

Remember, a generalized formula for clay is SILICA, ALUMINA, water and various impurities. Thus, the addition of ALUMINA to a glaze in the form of a clay actually introduces two of the three essential parts of a functional glaze: SILICA AND ALUMINA.

What minerals is a common clay mineral used for making pottery? ›

Pottery Clay Minerals

Because they can form large deposits, the most common clay minerals used by potters are kaolinite, montmorillonite and bentonite. These minerals are composed of hydrous aluminum silicate.

What elements are in clay minerals? ›

Clay minerals are composed essentially of silica, alumina or magnesia or both, and water, but iron substitutes for aluminum and magnesium in varying degrees, and appreciable quantities of potassium, sodium, and calcium are frequently present as well.

How to identify clay minerals? ›

Clay minerals are most often identified by reflection powder XRD of both oriented and random preparations. Identification is greatly facilitated if the clay fraction is first separated from the rock (bulk sample), to minimize contamination by non-clay minerals.

What are the four main types of clay minerals? ›

There are six main types of clay minerals (Swagata, 2003; Uddin, 2018): (i) kaolinite, (ii) smectite group, (iii) illite group, (iv) vermiculite, (v) chlorite and (vi) allophanes.

What are the three basic ingredients in glaze? ›

Glazes need a balance of the 3 main ingredients: Silica, Alumina and Flux. Too much flux causes a glaze to run, and tends to create variable texture on the surface. The texture may vary from shiny, where the glass is balanced, to matte where the excessive flux oxides may form visible, possibly lumpy, crystals.

Is salt glazed pottery safe? ›

Salt glazing involves throwing wet salt into the heated kiln while the bisque ware is being fired. If sodium chloride salt is added, hydrogen chloride gas is formed which is highly toxic by inhalation. Hydrogen chloride and water vapor also form corrosive hydrochloric acid which can corrode metal fittings in the area.

What is the genesis of clay minerals? ›

Clay minerals mostly form from pre-existing minerals, primarily from rock-forming silicates by transformation, and/or neoformation, where rocks are in contact with water, air, or steam. As Konta (1992) stated 'everything starts in weathering crust'.

What are natural clay minerals? ›

Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2Si2O5(OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Oxford Clay (Jurassic) exposed near Weymouth, England.

What is the most common mineral present in the clay? ›

Illite is similar to muscovite and is the most common clay mineral, often composing more than 50 percent of the clay- mineral suite in the deep sea.

Which mineral is most related to clay? ›

Kaolinite, smectite (in particular, montmorillonite/bentonite), illite, and talc are the most widespread clay minerals (Fig. 3). Different clay minerals may form at the same time, but the deposits are usually temperature-zoned.

What are the minerals in clay or clay? ›

Clay is natural, fine-grained (<2 or <4 μm), mainly constituted of phyllosilicates, plastic (except flint clays ), and hardens on drying or firing. On the other hand, clay mineral is natural or synthetic, without size criterion, might include nonphyllosilicates, plastic, and hardens on drying or firing.

What is an example of a clay mineral? ›

Clay minerals such as kaolinite, smectite, chlorite, micas are main components of raw materials of clay and formed in presence of water. A large number of clays used to form the different structure which completely depends on their mining source.

What are the 3 mineral components of soil? ›

Soil minerals are divided into three size classes — clay, silt, and sand (Figure 1); the percentages of particles in these size classes is called soil texture. The mineralogy of soils is diverse.

What are primary clay minerals? ›

A clay deposit that is near the site of erosion and alteration. They have more mechanical impurities and fewer chemical and mineralogical impurities. Primary clays have larger particles and less plasticity.

What are the three natural substances that clay is made up of? ›

Clay minerals are hydrous aluminium phyllosilicate minerals, composed of aluminium and silicon ions bonded into tiny, thin plates by interconnecting oxygen and hydroxide ions. These plates are tough but flexible, and in moist clay, they adhere to each other.

What are three properties of clay minerals? ›

These properties include: cation exchange capabilities, plastic behaviour when wet, catalytic abilities, swelling behaviour, and low permeability. They give to clay and clay-based minerals higher application in many industries and processes.

References

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